Hermann, A., Ashcroft, N. W. & Hoffmann, R. High pressure ices. Proc. Natl Acad. Sci. USA 109, 745–750 (2012).
Dubrovinsky, L., Dubrovinskaia, N., Prakapenka, V. B. & Abakumov, A. M. Implementation of micro-ball nanodiamond anvils for high-pressure studies above 6 Mbar. Nat. Commun. 3, 1163 (2012).
Cavazzoni, C. et al. Superionic and metallic states of water and ammonia at giant planet conditions. Science 283, 44–46 (1999).
Mattsson, T. R. & Desjarlais, M. P. Phase diagram and electrical conductivity of high energy-density water from density functional theory. Phys. Rev. Lett. 97, 017801 (2006).
Millot, M. et al. Nanosecond X-ray diffraction of shock-compressed superionic water ice. Nature 569, 251–255 (2019).
Zurek, E., Edwards, P. P. & Hoffmann, R. A molecular perspective on lithium-ammonia solutions. Angew. Chem. Int. Ed. 48, 8198–8232 (2009).
Thompson, J. C. Electrons in Liquid Ammonia (Clarendon Press, 1976).
Lodge, M. et al. Multielement NMR studies of the liquid-liquid phase separation and the metal-to-nonmetal transition in fluid lithium- and sodium-ammonia solutions. J. Phys. Chem. B 117, 13322–13334 (2013).
Buttersack, T. et al. Photoelectron spectra of alkali metal-ammonia microjets: from blue electrolyte to bronze metal. Science 368, 1086–1091 (2020).
Hutton, A. T. Dramatic demonstration for a large audience: the formation of hydroxyl ions in the reaction of sodium with water. J. Chem. Educ. 58, 506 (1981).
Mason, P. E. et al. Coulomb explosion during the early stages of the reaction of alkali metals with water. Nat. Chem. 7, 250–254 (2015).
Young, R. M. & Neumark, D. M. Dynamics of solvated electrons in clusters. Chem. Rev. 112, 5553–5577 (2012).
Mason, P. E., Buttersack, T., Bauerecker, S. & Jungwirth, P. A non-exploding alkali metal drop on water: from blue solvated electrons to bursting molten hydroxide. Angew. Chem. Int. Ed. 55, 13019–13022 (2016).
Suzuki, T. Ultrafast photoelectron spectroscopy of aqueous solutions. J. Chem. Phys. 151, 090901 (2019).
Alchagirov, B. B. et al. Surface tension and adsorption of components in the sodium–potassium alloy systems: effective liquid metal coolants promising in nuclear and space power engineering. Inorg. Mater. Appl. Res. 2, 461–467 (2011).
Addison, C. C. The Chemistry of Liquid Alkali Metals (Wiley, 1984).
Citrin, P. H. High-resolution X-ray photoemission from sodium metal and its hydroxide. Phys. Rev. B 8, 5545–5556 (1973).
Lueth, H. Surfaces and Interfaces of Solid Materials (Springer, 1997).
Kiskinova, M., Pirug, G. & Bonzel, H. P. Adsorption and decomposition of H2O on a K-covered Pt(111) surface. Surf. Sci. 150, 319–338 (1985).
Blass, P. M., Zhou, X. L. & White, J. M. Coadsorption and reaction of water and potassium on Ag(111). J. Phys. Chem. 94, 3054–3062 (1990).
Nachtrieb, N. H. Self-diffusion in liquid metals. Adv. Phys. 16, 309–323 (1967).
Ketteler, G. et al. The nature of water nucleation sites on TiO2(110) surfaces revealed by ambient pressure X-ray photoelectron spectroscopy. J. Phys. Chem. C 111, 8278–8282 (2007).
Kittel, C. Introduction to Solid State Physics (Wiley, 2005).
Abelès, F., Borensztein, Y., Decrescenzi, M. & Lopezrios, T. Optical evidence for longitudinal-waves in very thin Ag layers. Surf. Sci. 101, 123–130 (1980).
Winter, B., Faubel, M., Vacha, R. & Jungwirth, P. Behavior of hydroxide at the water/vapor interface. Chem. Phys. Lett. 474, 241–247 (2009).
Bonzel, H. P., Pirug, G. & Winkler, A. Adsorption of H2O on potassium films. Surf. Sci. 175, 287–312 (1986).
Hart, E. J. & Boag, J. W. Absorption spectrum of hydrated electron in water and in aqueous solutions. J. Am. Chem. Soc. 84, 4090–4095 (1962).
Barzynski, H. & Schulte-Frohlinde, D. On the nature of the electron traps in alkaline ice. Z. Naturforsch. A 22, 2131–2132 (1967).
Kevan, L. Slovated electron structure in glassy matrices. Acc. Chem. Res. 14, 138–145 (1981).
Buttersack, T. et al. Deeply cooled and temperature controlled microjets: liquid ammonia solutions released into vacuum for analysis by photoelectron spectroscopy. Rev. Sci. Instrum. 91, 043101 (2020).
Seidel, R., Pohl, M. N., Ali, H., Winter, B. & Aziz, E. F. Advances in liquid phase soft-X-ray photoemission spectroscopy: a new experimental setup at BESSY II. Rev. Sci. Instrum. 88, 073107 (2017).
Sawhney, K. J. S., Senf, F. & Gudat, W. PGM beamline with constant energy resolution mode for U49-2 undulator at BESSY-II. Nucl. Instrum. Methods Phys. Res. Sect. A 467, 466–469 (2001).
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